Name: COF-300
Other names: 1,4-Benzenedicarboxaldehyde, polymer with 4,4 ",4 ",4 "-methanetetrayltetrakis[benzenamine]
CAS: 1133843-97-6
Unit molecular formula: [C12H18N4O4.C9H6O3]
Unit molecular weight: 444.44
Monomer: Tetra(4-anilyl)methane (CAS: 60532-63-0); Terephthalaldehyde (623-27-8)
Aperture: 0.8nm
Pore volume: 0.8cm3 /g
Specific surface: BET specific surface > 1200 m2/g
Product appearance: Orange/yellow powder
1. Stability
1) COF-300 is relatively stable and can be stored for several weeks. It is stable in aqueous solution and common organic solvent
2. Preservation and activation methods
1) Under normal or low temperature conditions, dry sealed storage
3. Other features
Fluorescence :NA
4. Application field
1) Gas storage materials and gases and voc or small molecule adsorption materials
2) COF-300 has a rigid 3D three-dimensional structure and is a good catalyst carrier
References: 1) Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu; Kloeck, Cornelius; O'Keeffe, Michael; Yaghi, Omar M.; J. Am. Chem. Soc. 2009, 131(13), 4570-4571, DOI: 10.1021/ja8096256; A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
2) Fischbach, Danyon M.; Rhoades, Grace; Espy, Charlie; Goldberg, Fallon; Smith, Brian J.; Chem. Commun. 2019, 55(25), 3594-3597, DOI: 10.1039/c8cc09571j; Controlling the crystalline structure of imine-linked 3D covalent organic frameworks
3) Zhu, Dongyang; Zhang, Zhuqing; Alemany, Lawrence b.; Li, Yilin; Nnorom, Njideka; Barnes, Morgan; Khalil, Safiya; Rahman, Muhammad m.; Ajayan, Pulickel m.; Verduzco, Rafael; Chem. Mater., 2021, 33 (9), 3405-3411, DOI: 10.1021 / acs chemmater. 1 c00737; Rapid, Ambient Temperature Synthesis of Imine Covalent Organic Frameworks Catalyzed by Transition-Metal Nitrates
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